| 曹九超,俞 晔,朱 云,金青哲.食用油中5种邻苯二甲酸酯的液液萃取-固相萃取耦合富集和气质联用的测定[J].中国油脂,2014,39(1):.[CAO Jiuchao,YU Ye,ZHU Yun,JIN Qingzhe.Determination of five phthalate acid esters in edible oil by GC-MS and coupled enrichment of liquid-liquid extraction and solid phase extraction[J].China Oils and Fats,2014,39(1):.] |
| 食用油中5种邻苯二甲酸酯的液液萃取-固相萃取耦合富集和气质联用的测定 |
| Determination of five phthalate acid esters in edible oil by GC-MS and coupled enrichment of liquid-liquid extraction and solid phase extraction |
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| DOI： |
| 中文关键词: 塑化剂 邻苯二甲酸酯 食用油 固相萃取 GC-MS |
| 英文关键词:plasticizer phthalate acid esters edible oil solid-phase extraction GC-MS |
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| 中文摘要: |
| 建立了食用油中常见的5种邻苯二甲酸酯（PAEs）类塑化剂的检测方法。食用油样品经乙腈提取后进行冷冻脱脂处理、玻璃ProElut PSA 固相萃取柱净化，GC-MS全离子扫描定性、选择离子监测模式(SIM)定量。结果显示：食用油中5种PAEs加标回收率在76.17%~98.81%之间，相对标准偏差在1.01%~7.20%之间。该方法的仪器检出限（信噪比为3）和最低定量限分别在0.3~2.0 μg/L 及1.0~20.2 μg/kg之间。该方法检测食用油中PAEs类塑化剂具有较高的准确度和灵敏度。 |
| 英文摘要: |
| A method for determination of five common phthalate acid esters（PAEs） in edible oil was established. The edible oil samples were extracted by acetonitrile and then frozen to defat，and cleaned up with glass ProElut PSA solid phase extraction column. The qualitification and quantification of the five PAEs were performed by GC-MS in full ion scanning and selected ion monitoring （SIM） mode respectively. The results showed that the average recovery rates of standard addition of the five PAEs in edible oil ranged from 76.17% to 98.81% with 1.01%-7.20% of the relative standard deviations. The instrumental detection limits （S/N=3）of the method ranged from 0.3 μg/L to 2.0 μg/L，and the limits of quantitation were 1.0-20.2 μg/kg. This method for the determination of the five PAEs in edible oil had high accuracy and sensitivity. |
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