| 张斌，孙兰萍，伍亚华，许晖，屠康.花生壳总黄酮的大孔树脂吸附动力学研究[J].中国油脂,2017,42(03):.[ZHANG Bin，SUN Lanping，WU Yahua，XU Hui，TU Kan.Adsorption kinetics of flavonoids from peanut hull by macroporous resin[J].China Oils and Fats,2017,42(03):.] |
| 花生壳总黄酮的大孔树脂吸附动力学研究 |
| Adsorption kinetics of flavonoids from peanut hull by macroporous resin |
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| DOI： |
| 中文关键词: 花生壳总黄酮 大孔树脂 吸附动力学 |
| 英文关键词:peanut hull flavonoids macroporous resin adsorption kinetics |
| 基金项目: |
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| 中文摘要: |
| 以花生壳为原料，采用乙醇提取花生壳中的总黄酮，并用大孔树脂吸附花生壳总黄酮。研究了吸附过程中温度对吸附量的影响，并绘制静态吸附动力学曲线，根据静态平衡吸附量分别绘制颗粒内扩散、准一级吸附和准二级吸附的3种动力学拟合曲线，并计算3种动力学模型参数。结果表明：温度对大孔树脂吸附花生壳总黄酮的吸附量具有显著性的影响，该过程是一个吸热过程；吸附速率受到液膜扩散和颗粒内扩散共同控制；确定了大孔树脂吸附花生壳总黄酮的准一级吸附动力学模型公式，并通过Arrhenius方程计算得到吸附过程的活化能Ea为7.96 kJ/mol，该过程是一个物理过程。 |
| 英文摘要: |
| With peanut hull as raw material， flavonoids were extracted from peanut hull by ethanol and were adsorbed by macroporous resin. The effects of temperature on the adsorption capacity were studied， and the static adsorption kinetics curve was drawn. According to the static equilibrium adsorption amount ，three kinds of adsorption kinetics fitting curves were drawn， including inter-particle diffusion， pseudo-first-order adsorption and pseudo-second-order adsorption， and three kinds of kinetics model parameters were calculated. The results showed that temperature had significant effect on the adsorption capacity of peanut hull flavonoids by macroporous resin， and the process was an endothermic process. The adsorption rate was controlled by the diffusion of liquid film and the inter-particle diffusion. The pseudo-first-order kinetics model for the adsorption of peanut hull flavonoids by macroporous resin was determined. The activation energy (Ea) was 7.96 kJ/mol calculated by the Arrhenius formula， and it was a physical process. |
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