李法社,李 明,包桂蓉,等.生物柴油原料油的理化性能指标分析[J].中国油脂,2014,39(2):.[LI Fashe,LI Ming,BAO Guirong,etc.Physicochemical properties of biodiesel feedstock oils[J].China Oils and Fats,2014,39(2):.] |
生物柴油原料油的理化性能指标分析 |
Physicochemical properties of biodiesel feedstock oils |
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DOI: |
中文关键词: 生物柴油原料油 理化特性 氧化稳定性 |
英文关键词:biodiesel feedstock oil physicochemical property oxidation stability |
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中文摘要: |
对17种生物柴油原料油分别进行密度、运动黏度、硫含量、酸值和氧化稳定性等性能指标的分析测定。结果表明:密度相差不大,其密度(20℃)在0.89~0.93 g/cm3之间,且随温度升高而降低;运动黏度均超过30 mm2/s,地沟油的最大,达到62.64 mm2/s;硫含量均相对较低,芝麻油的硫含量最高,达到201.48 mg/L;酸值(KOH)相差较大,大豆油的最低,为1.31 mg/g,地沟油的最大,达到164.47 mg/g,经过720 d的存放,小桐子油和橡胶籽油的酸值是原来的5.58倍和5.53倍;蓖麻籽油的氧化稳定性最好,诱导期时间达到39.10 h,地沟油的最差,诱导期时间为1.07 h,在两年的存放时间内,小桐子油诱导期时间从15.90 h降为5.24 h。 |
英文摘要: |
The density, kinematic viscosity, acid value, sulfur content and oxidation stability of seventeen kinds of biodiesel feedstock oils were determined and analyzed. The results showed that the densities (20℃)of the oils were 0.89-0.93 g/cm3 and they decreased with temperature rising; all the kinematic viscosities were higher than 30 mm2/s, in which swill-cooked dirty oil reached 62.64 mm2/s; sulfur contents were relatively low, while sesame oil was especially high, reaching 201.48 mg/L; acid values had significant difference among the oils with the highest of swill-cooked dirty oil (164.47 mgKOH/g) and the lowest of soybean oil (1.31 mgKOH/g), and the acid values of Jatropha curcas
L. seed oil and rubber seed oil were 5.58 and 5.53 times of their fresh oils after storage for 720 d; the oxidation stability of castor seed oil was the best with induction period reaching 39.10 h, while that of swill-cooked dirty oil was the worst with 1.07 h of the induction period, and the induction period of Jatropha curcas L. seed oil shortened from 15.90 h to 5.24 h after storage for two years. |
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