Two-step catalytic production of biodiesel from waste clay oil
  
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KeyWord:waste clay oil  two-step method  biodiesel  esterification  transesterification
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Author NameAffiliation
GAO Xiaolong  
TAN Chuanbo  
WU Suxi  
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Abstract:
      Biodiesel was producted from waste clay oil by two-step catalytic method of esterification and transesterification.With ferric sulfate as catalyst in esterification reaction and sodium hydroxide as catalyst in transesterification reaction, the conditions of the two-step catalytic method were optimized by orthogonal experiment.The results showed that the optimal esterification conditions were obtained as follows: ferric sulfate dosage 4%, molar ratio of methanol to oil 14∶1, reaction temperature 70℃, reaction time 3 h; and the optimal transesterification conditions were obtained as follows: molar ratio of methanol to oil 6∶1, sodium hydroxide dosage 1.4%, reaction temperature 70℃, reaction time 2.5 h. Under these optimal conditions, the total transesterification rate reached 96.4%, and the main quality indicators of the biodiesel obtained were close to that of 0# diesel.
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